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WIPP Environmental
Monitoring Project
Project Concept
As defined in the original grant language,
the purpose of the WIPP EM project is to establish and maintain independent
environmental research and monitoring in the vicinity of the WIPP and to
make the results easily accessible to all interested parties. This project
is being implemented during the WIPP pre-disposal phase, and will continue
into the operational (disposal) phase. The WIPP EM project is organized
and carried out independent of direct oversight by DOE, and the project
does not provide data to any regulatory body to meet the compliance demonstration
requirements applicable to the WIPP.
Study Design
for the WIPP EM
A primary objective of the WIPP EM
pre-disposal baseline phase is to quantify the existing environmental levels
of the radionuclides and inorganic non-radioactive constituents that are
known or expected to occur in the wastes to be deposited at the WIPP. These
data will serve as a basis for comparison against data collected for the
same constituents after the WIPP begins operation, and extending into the
post-operational phase. A true quantification requires application of specialized
methods, particularly in radiochemistry, to produce data that are free
of non-detect values. It is also important to note that the objective requires
sampling designs that provide data to characterize the spatial variation
in the analytes of interest across the natural landscape in the vicinity
of the WIPP, and the temporal variation in the analytes of interest with
respect to seasonal and interannual ecosystem fluctuations. For example,
the current concentrations of Pu in aerosols in the vicinity of the WIPP
span a range of values that may be dependent on such factors as localized
soil type and seasonal weather variations that impact resuspension.
The WIPP EM incorporates analyses of
a variety of inorganic substances as part of the routine monitoring design.
According to information contained in the Waste Isolation Pilot Plant Hazardous
Waste Draft Permit, (dated 15 May 1998, Section II.C.3 Permitted TRU Mixed
Wastes), the mixed waste to be placed at the WIPP may contain arsenic,
barium, beryllium (powder), cadmium, chromium, copper, lead, mercury, nickel,
selenium, and silver. These constituents are naturally-occurring elements,
and are also produced as contaminants from other anthropogenic sources,
so quantification of pre-operational levels in the WIPP region is needed
to evaluate potential future releases. Some of these trace elements are
of concern due to possible toxicological effects for humans and ecosystems.
From a practical standpoint, they are also very important and useful in
the WIPP EM project as chemical tracers. The sources for these metals are
reasonably well known, even on global scales (Nriagu, J. O. and J. M. Pacyna,
1988, Nature, 333:134), and they are readily determined in various
types of environmental media.
If contaminant releases from the WIPP
were known or suspected, it would become critical to predict the movements
of the contaminants within the ecosystem. A second major objective of the
WIPP EM baseline studies is to gather information concerning the basic
structural/chemical composition of environmental media and ecosystem processes
that could be applied in such predictive modeling. Concurrent analyses
of naturally occurring radionuclides, non-radioactive elements, and target
ions (such as nitrate and sulfate), provide an understanding of the complex
and interlocking biogeochemical cycles that characterize the WIPP surface
environment. Such characterization provides the basis for modeling of ecosystem
processes that determine the fate and transport of contaminants of concern.
The following sections present a brief
description of the basic sampling design for each major environmental medium
in the WIPP EM, including some primary considerations that serve as the
basis of the design. In addition to the core sampling and analyses, information
is provided on ancillary studies that are planned or in progress.
Aerosols
Aerosols are considered a prime environmental
medium of concern with respect to potential future releases by the WIPP
because airborne contaminants can rapidly disperse, can be transported
over long distances, and represent a significant mode for uptake by humans
and other organisms. CEMRC studies of aerosols focus on both man-made and
naturally-occurring radionuclides (including those known or expected to
occur in the wastes to be deposited at the WIPP) and selected non-radioactive,
inorganic constituents.
Aerosol sampling is conducted at four
locations as part of the WIPP EM, with samplers operating continuously
at each location. The locations include a port inside the WIPP exhaust
shaft, a site approximately 0.1 km northwest (downwind) of the WIPP exhaust
shaft (On Site station), a site approximately 1 km northwest (downwind)
of the WIPP (Near Field station), and a site approximately 19 km southeast
(upwind) of the WIPP (Cactus Flats station) (Fig.
2). The sites were selected on the basis of the prevailing wind directions
at the WIPP. In designing aerosol studies, it is widely recognized that
there is seldom a satisfactorily defined "control" location
that is far enough from a source to ensure isolation from aerosol releases,
while adequately replicating key ecological features of aerosol composition,
soil, topography, biota and weather conditions. The Cactus Flats location
represents a reasonable compromise to approximate a control location for
surface parameters, based on average conditions.
Sampling in the WIPP exhaust shaft
(Station A) consists of collection of one filter daily (Monday through
Friday) from
a Fixed Air Sampler (FAS), that is operated with an average
air flow of 56 L min-1. The daily FAS samples will be subjected
to gross alpha/beta counting individually. The five daily (Monday - Friday)
samples from each week will be composited for weekly gamma counting and
all weekly composites will be combined each calendar quarter for analyses
of Pu and Am by alpha spectrometry. This sampling is a workplace monitor
that will provide a gross check of emissions on a short resolution time-scale
(for daily and weekly samples), with a higher sensitivity check for cumulative
emissions over a three-month time scale. (Collection of FAS samples by
the CEMRC began in December 1998, and sample analyses will begin in July
1999).
At the other three stations, aerosol
samples for radionuclide analyses are collected using high-volume samplers
(approximately 1.13 m3
min-1). These samplers are
operated to maximize particulate loading without impacting air flow, so
individual samples are collected for periods ranging from three to six
weeks, depending on levels of particulate deposition. By focusing on high
particulate loading, this sampling allows collection of sufficient mass
for quantitative determination of the manmade alpha-emitting radionuclides
(Pu and Am) at background levels via alpha spectrometry, which has been
of particular interest in baseline studies. Low-volume samplers (10 L min-1)
are operated for collection of samples for analyses of non-radioactive,
inorganic constituents (trace metals and selected ionic compounds). Analytical
methods for inorganic constituents do not require large sample concentrations,
so low-volume sampling includes two 2-day samples, and one 3-day sample
weekly.
All three stations support one high-volume
sampler collecting total suspended particulate (TSP) matter and one low-volume
sampler collecting TSP. The Near Field and Cactus Flats stations also support
a second high-volume sampler collecting particulate matter less than 10
m
m aerodynamic equivalent diameter (PM10), and two other low-volume
samplers, one collecting particulate matter less than 2.5 m
m aerodynamic equivalent diameter (PM2.5) and one collecting
PM10. With respect to human health, PM10 and PM2.5
are the particulate classes that are generally recognized as the most significant
of the respirable aerosol components, and it is important to characterize
the natural temporal and spatial variation in these components that would
impact potential uptakes of WIPP contaminants by humans.
Additional studies in progress include
concurrent operation of a dichotomous sampler at the Near Field station
since February 1998 and at the Cactus Flats station since November 1998.
The dichotomous sampler is an EPA-equivalent reference method for sequential
measurement of both PM10 and PM2.5. The mass loading
and inorganic constituents will be compared between the dichotomous sampler
and the low-volume samplers to evaluate possible future substitution of
the dichotomous samplers, and to allow comparisons with data from the low-volume
samplers with other results using dichotomous samplers.
Soils
Soils are of high interest to the WIPP
EM because aerosol releases of contaminants would eventually be deposited
in surface soils, which then can serve as a source for continuing contaminant
exposure and uptake via direct contact, food chain pathways, and re-suspension.
From this perspective, soil is an integrating medium of primary concern
in predictive ecosystem and contaminant transport modeling, that requires
good information about the dispersion of analytes of concern across the
landscape.
The soil sampling design for the WIPP
EM baseline and future monitoring studies is organized to address analyte
variability on three spatial scales. First, soil sampling is conducted
within a 166 km2
area centered on the WIPP operations facility,
and at a comparable area encompassing the Cactus Flats aerosol sampling
station. Within each of these two areas, samples are collected at 16 locations
positioned in concentric rectangular grids (Fig
2). At each of the 16 locations in each area, samples are collected
at three randomly selected sites within 25-m of the location’s reference
point. Individual sampling sites are selected on the basis of relatively
flat topography and minimum surface erosion or disturbance due to human
or livestock activity. The resulting data represent 96 discrete samples
that provide for estimation of variability at the small-scale (between
samples within a .0025 km2 area), medium-scale (among locations
within each 166 km2 area), and large-scale (between the two
sampling areas located approximately 19 km apart). This type of design
has been applied in other experimental studies focusing on analyte dispersion
patterns in soils (Gilbert, R.O., 1987, Statistical Methods for Environmental
Pollution Monitoring, Van Nostrand Reinhold Co., New York).
During baseline studies, samples for
pilot projects were collected at various times in 1996 and 1997 using this
spatial design. In 1998, the full suite of 96 samples was collected during
March-April. In 1999 and subsequent years, the full suite of 96 samples
will be collected once annually, during January-February. The limitation
of soil sampling to one period annually is based on the assumption that
any input of contaminants to surface soils from WIPP releases would occur
via aerosol deposition, and since aerosol sampling is conducted continuously,
more frequent soil sampling is not warranted unless there was evidence
of a contaminant increase in aerosols.
Surface
Water and Sediments
The WIPP EM incorporates studies at
three reservoirs on the Pecos River, which is the major perennial fresh
water system closest to the WIPP that has extensive human usage. The three
reservoirs are: Brantley Lake, located approximately 40 miles northwest
of the WIPP; Lake Carlsbad, located in Carlsbad and approximately 25 miles
northwest of the WIPP; and Red Bluff Lake, located approximately 30 miles
southwest of the WIPP. Surface and underground drainage from the area of
the WIPP is to the southwest, and Red Bluff Lake is downstream of the area
where drainage from the WIPP area enters the Pecos River. Brantley Lake
and Lake Carlsbad are both upstream of the WIPP area drainage, and thus
would be unlikely to receive contaminants
via drainage from the
vicinity of the WIPP but could be contaminated by atmospheric deposition.
In addition to their proximity to the WIPP, these three reservoirs were
selected because of the potential exposure of human populations to contaminants
through use by the local population for sport fishing and recreation, and
through use of Pecos River water for agricultural irrigation in a large
region of the river floodplain throughout New Mexico and Texas.
During 1996-97, pilot studies were
conducted to identify shallow, mid- and deep-basin areas of each reservoir
and to characterize the physical and chemical nature of the sediments at
the various depths. The deep basin areas now serve as the focus for sediment
sampling because radioactive contaminants (and other inorganic contaminants)
are known to concentrate in zones featuring fine-grained sediments, which
are highest in the deepest waters. The sediment sampling consists of collection
of one sample from each of four randomly selected locations within the
deep basins at each reservoir. Each sample analyzed is a composite of two
to four grab samples taken from the top 5-10 cm of the sediment surface.
Two samples of water (one at the surface and one approximately 0.5 to 1
m above the sediment bed) are also collected at one deep basin site at
each reservoir. During 1997-1998, sediment and surface water samples were
collected once during the spring, once in winter, and once in the summer.
Because of the distance between the WIPP site and these reservoirs, the
potential risk of direct contamination of the reservoirs by releases from
the WIPP is relatively low compared to other media, and sampling in subsequent
years will be conducted once annually in the summer.
Drinking
Water
The WIPP EM studies of ground water
focus on the major drinking water supplies used by communities in the WIPP
region because these are often perceived by the public as a potential route
for contaminants to reach humans. However, studies of the hydrogeology
of the region suggest (1) that the risk is low for contaminants from the
WIPP to reach the various regional underground aquifers that are used as
sources of drinking water, and (2) the movement of contaminants into these
aquifers, if it occurred, would be extremely slow (DOE, 1997, Waste Isolation
Pilot Plant Disposal Phase Final Supplemental Environmental Impact Statement,
DOE/EIS-0026-S-2). Five community supplies of drinking water (representing
three major regional aquifers) are included in routine sampling, including
Carlsbad, Loving/Malaga, Otis, Hobbs, and a secondary source for Carlsbad.
One private water well (representing a fourth aquifer) that is located
within ten miles of the WIPP is also sampled because it is the only private
well in close proximity to the WIPP that is known to have been used for
human consumption in recent years, and because it draws from the aquifer
considered most likely to be contaminated by releases from the WIPP into
ground water, (DOE, 1990, Final Supplemental Environmental Impact Statement,
DOE/EIS-0026-FS).
Studies of the drinking water sources
utilize samples collected at locations in the drinking water systems that
are considered to be representative of the overall supply to the system’s
user group. Many of the systems draw from several wells simultaneously
or on a rotating basis, and routinely sampling all of the dozens of individual
wells is not justified. Instead, samples for municipal systems are drawn
from the primary reservoir vessels downstream of the well sources, which
are more representative of the overall water supply than samples from individual
wells. Likewise, for municipal supplies, samples are not taken from individual
user taps because of the potential contamination introduced via the residential
segments of the system, which would have no demonstrable relationship to
contaminants from the WIPP. Recharge of the target aquifers is not known
to be strongly linked to seasonal cycles (except in a few cases where an
indirect linkage via hydraulic head pressure is suspected). Therefore,
there is little basis to expect any significant seasonality in drinking
water contaminants of concern, and the WIPP EM sampling design for drinking
water does not incorporate a seasonal component.
During initial baseline studies in
1996-1998, the drinking water samples were subjected to a suite of analyses
for over 150 analytes, including those that are regulated under the Safe
Drinking Water Act, and contaminants known or suspected to be present in
the WIPP wastes. In addition to serving as a baseline for future comparisons,
these analyses provided information that was considered to be of general
interest to the public. Knowledge of the basic chemical composition of
the water supplies is also useful in radioanalytical studies, where chemical
processes can be strongly affected by non-radioactive components.
In relation to the core objectives
of the WIPP EM, radioanalyses of drinking water conducted during 1997-1998
were unable to detect Pu or Am in any of the samples collected. The analyses
applied to the samples consisted of traditional alpha spectrometry. Samples
of drinking water have also been submitted for thermal ionization mass
spectrometry (TIMS) (a potentially more sensitive radioanalytical technique)
and results will be reported during the next annual cycle. If the TIMS
analyses do not detect any of the manmade actinides of interest, each of
the six drinking water supplies will continue to be sampled once annually
for selected radiological and inorganic testing, but analyses for man-made
actinides will only be repeated with gross detection limits until after
WIPP begins operation.
Biota
Studies of biota for the WIPP EM have
focused on native vegetation because the vegetation is consumed by beef
cattle, and consumption of beef from cattle pastured in the vicinity of
the WIPP could serve as an exposure pathway to humans for contaminants
released from the WIPP. While it would seem more desirable to monitor the
presence of contaminants in the beef directly, the livestock industry in
the region routinely uses supplemental feeding for range cattle during
some portion of most years. This means that the cattle are potentially
exposed to contaminants from distant sources via the supplemental feeding,
thereby confounding the interpretation of any direct analyses of range
cattle tissues. Secondarily, if the occurrence of radioactive contaminants
in major food plants is known, the potential uptake of radioactive contaminants
by range cattle can be effectively predicted from existing data on livestock
diets, consumption rates, and absorption ratios.
During baseline studies, vegetation
samples have been collected from a total of six species of plants that
serve as preferred forage species for cattle during at least some portion
of the year. These include fall witchgrass (Leptoloma cognatum),
sand paspalum (Paspalum setaceum), spike dropseed (Sporobolus
contractus), mesa dropseed (S. flexuosus), honey mesquite (Prosopus
glandulosa), and shinnery oak (Quercus havardii). The sampling
includes collection of discrete samples of each species, because relevant
published work indicates that plant species can vary significantly in both
uptake of radionuclides into plant tissues and in adherence of radiation-contaminated
soil particles to external plant surfaces.
Vegetation is sampled twice annually
during the two major periods of new growth for native vegetation (March-May
and August-October). Not all of the same species can be sampled at each
period because some of the species only produce major new growth during
one season, and because the abundance of the species varies among years
depending on weather patterns. Six samples of each of three species (contingent
on availability) are collected during each sampling period from selected
sites on the sampling grid surrounding the WIPP (which encompasses the
Near Field aerosol sampling station). The vegetation samples are analyzed
for selected radionuclides only. Collecting samples at the same locations
used for soils allows for a direct comparison between radionuclide levels
measured in soils and vegetation. Vegetation sampling will continue to
be conducted twice annually during both baseline and operational monitoring
phases.
Additional studies are in progress
to evaluate the effectiveness of expanding the biota sampling for radionuclides
to include arthropods. In many desert ecosystems, total arthropod biomass
has been shown to equal or exceed total biomass for any other consumer
component, and arthropod communities encompass primary, secondary and tertiary
consumers, as well as detritivores and necrovores. As such, arthropods
could be used to study the movement of radionuclides through natural ecosystem
food chains.
Human Population
The "Lie
Down and Be Counted" project serves as a component of the WIPP
EM that directly addresses the general concern about personal exposure
to contaminants shared by residents who live near many DOE sites. Although
this aspect of the project could be viewed as using local residents as
monitors of contaminant release from the WIPP, the design of wide-scale
monitoring of other media ensures (as much as reasonably possible) that
contaminant releases would be detected in the environment long before significant
contact with human residents. It is important to note that an individual
who is determined to have internally deposited radioactive materials after
the WIPP begins operation, could not use the results of this study to suggest
that the uptake occurred as a result of exposure to materials at the WIPP
unless that individual had been subject to an in vivo bioassay a
priori, with negative results.
As in other aspects of the WIPP EM,
in
vivo bioassay testing has been used to establish a baseline profile
of internally-deposited radionuclides in a sample of local residents. The
sampling design included solicitation of volunteers from all segments of
the community, with sample sizes sufficient to meet or exceed a 15% range
margin of error for comparisons between major population ethnicity and
gender categories as identified in the 1990 census. The minimum sample
size threshold was achieved for the major categories early in 1998, and
is as low as 8% margin of error range for some categories. Baseline sampling
will continue to expand the sample size (and thereby increase statistical
power) until the WIPP begins operation. After the WIPP begins operation,
bioassays of the original volunteer cohort will be repeated on a schedule
of once every two years, and additional new volunteers will be incorporated
each year to create replacements for attrition from the original cohort.
Meteorological
Monitoring
Fully automated meteorological stations
are operated by the CEMRC at the Near Field aerosol station and the Cactus
Flats aerosol station. Details concerning the sensors and operation of
the equipment are presented in the section on meteorology. The data derived
from these stations is essential to interpreting results from other parts
of the project, particularly the aerosol studies. For example, notable
short-term changes in aerosol compositions can be evaluated against wind
direction to determine if there were a possible difference in source terms.
Analyses
and Release of Data
The scheduling and management of sample
analyses collected in the WIPP EM project is based on (1) priorities for
providing information to the public in a timely manner, (2) relative risks
of human exposure to contaminants among the various media sampled, (3)
needs for stringent data validation and verification prior to release,
and (4) time constraints resulting from sample preparation and analysis
procedures. Based on this, and as noted previously, analyses of daily and
weekly composite FAS aerosol samples provide gross data on radiation at
a location immediately adjacent to the waste-handling and deposition activities.
The analytical results will be made available within a few weeks of sample
collection, and these data (along with quarterly composite data) will be
posted on the CEMRC DATA page quarterly. This is a routine, quick turnaround monitoring strategy
that focuses on detection of potential short-term, large-scale radioactive
contaminant release via the medium likely of most risk for worker
and public exposure (aerosols).
The project currently has archived
high-volume aerosol samples from the On Site, Near Field and Cactus Flats
stations that were collected beginning in 1997. Following completion of
radioanalyses of these archived samples during 1999, subsequent aerosol
analyses will be carried out with quarterly "batches" of filters, with
results posted on the web page approximately one month after the end of
each quarter.
For samples of soils, sediments, surface
water, drinking water and biota, collection is annual or semi-annual (as
previously described), and the period of time required for completion of
analyses varies with each medium. As for aerosols, archived samples of
other media are currently awaiting radioanalyses that will be completed
and reported in 1999. Subsequently, analytical results for these media
areas will generally be posted to the web site within six months after
sample collection.
Cumulative summaries and analyses of
the data from the Lie Down and Be Counted project are reported in each
year’s annual report. Beginning in 1999, summaries will also be provided
via a newsletter sent to volunteers. Because these data are considered
confidential, individual bioassay results are not presented in any reporting.
The management plan for the WIPP EM
incorporates milestones representing significant products and progress,
including both routine sampling and analyses and special studies. Key performance
indicators that integrate groups of milestones are identified and reviewed
annually to serve as metrics of the successful progress of the project.
Completion of 1998 key performance indicators is summarized in Appendix
I. Nine indicators were completed on time and four indicators were
delayed but completed prior to year-end. Three out of 16 indicators were
not completed, with 0-10% progress on each. Key performance indicators
for 1999 have been identified to serve as the basis for the 1999 WIPP EM
project schedule (Table
2).
Table 2. Key Performance
Indicators for 1999
Focus Area
|
Key Performance Indicator
|
| Aerosols |
1. Continue concurrent high-volume
and low-volume sampling and
analysis at current three locations
through 1999 |
2. Continue collection of
daily FAS samples in WIPP exhaust shaft
through 1999 |
| Soils |
3. Collect samples at current
32 locations during January-February
1999 |
| Meteorology |
4. Continue concurrent operation
of sampling stations at two current
sites through 1999 |
| Drinking water |
5. Collect samples from
six sources during March-April 1999 |
| Sediment and surface water |
6. Collect samples from
three reservoirs during June-July 1999 |
| Biota |
7. Collect vegetation samples
from six locations during spring and fall
1999 |
8. Collect composite arthropod
sample from one location during
April-November 1999 |
| Human studies |
9. Continue in vivo
bioassays for public |
| Radioanalyses |
10. Complete analyses of
all 1998 aerosol, soil, sediment, surface
water, drinking
water, and vegetation samples by October 1999 |
11. Complete FAS sample
analyses to meet quarterly posting
schedule, beginning
with July 1999 |
| Non-radiological analyses |
12. Complete analyses of
representative subset of 1999 low-volume
aerosol, soil,
sediment, surface water and drinking water samples
within three
months after each sample collection |
| Data management
and dissemination |
13. Implement electronic
Laboratory Information Management
System by October
1999 |
14. Post results of radioanalyses
of 1998 samples within two months
after completion
of analyses of each set of samples |
15. Post results of non-radiological
analyses of 1999 samples within
two months after
completion of each set of samples |
16. Make CEMRC 1998 Report
and background data accessible via
Internet by March
1999 |
17. Submit manuscript
for publication by July 1999 on radioanalyses
of soils |
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